Pulse radiolytic studies on cis-dichlorobis(1,10-phenanthroline-5,6-dione)Cobalt(III) complex
نویسندگان
چکیده
منابع مشابه
Pulse radiolytic studies of metallic clusters in a quaternary microemulsion system
The radiation-chemicalreduction of TlC, Co2C and Ni2C ions in water-in-oilmicroemulsion has been described. Rate constants for the reduction of the metal ions by eaq were found to be much lower compared to those in aqueous solution. The absorption spectrum and the rate constants of formation of the transient intermediates of metal clusters were correlated with the water-pool size, surrounding e...
متن کاملcis-Dichloridobis(1,10-phenanthroline)chromium(III) chloride
In the title complex, [CrCl(2)(C(12)H(8)N(2))(2)]Cl, the Cr(III) ion is situated on a twofold rotation axis and displays a slightly distorted octa-hedral CrCl(2)N(4) coordination geometry. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline and two chloride ligands. The chloride counter-anion exhibits half-occupation and is equally disordered over two positions.
متن کاملcis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a ne...
متن کاملStudies on the Venous Pulse
This investigation comprises a study of venous pulse, carotid, cardiographic, and heart sound records from twenty-one men with normal hearts. The heart sounds were recorded by the method of Einthoven. When correction is made for transmission, the first heart sound begins, on an average, 0.131 of a second before the c-wave of the venous pulse, and has an average duration of 0.128 of a second. Th...
متن کاملcis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate
In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) mol-ecules and two chloride ligands in a distorted octa-hedral geometry. In the crystal structure, a cavity is created by six complex mol-ecules connected by C-H⋯π inter-actions and non-classical C-H⋯Cl hydrogen bonds. The cavities...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2010
ISSN: 0974-3626,0973-7103
DOI: 10.1007/s12039-010-0026-7